Product ID:01379500 BENZOTRIAZOLE
MSDS Date:11/01/1994
FSC:6810
NIIN:01-448-9170
MSDS Number: CFMXJ

Emergency Phone: 201-796-7100/800-424-9300(CHEMTREC)

Info Phone: 201-796-7100 OR 201-796-7523

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

BENZOTRIAZOLE

CAS: 95-14-7

RTECS: DM1225000

Fraction By Weight: 100%

LD50 LC50 Mixture:1072MG/KG ORAL-RAL LD50
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRIT-INHAL,EYE.TOXIC BY
INHAL;MODERATE TOXIC BY DERMAL ABSORPTION & INGEST.INHAL:MAY CAUSE
IRRIT.IRRIT/TOXIC.SKIN:MAY CAUSE IRRIT.CHRONIC:MAY CAUSE CONTACT
DERM.POSITIVE ECZEMATOUS RXS OBSERVED IN PA TCH
TESTING.EYE:IRIT.MAY CUASE SEFVERE IRRIT,POSSIBLY
BURNS.CHRONIC:REP/RPOL CONTACT W/IRRIT MAY CAUSE CONJUNCT(SUPPLE)
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN STATUS:NONE.
Effects of Overexposure:INHAL:IRRIT.SKIN IRRIT,DERM,EYE IRRIT,POSSIBLEY
EYE BURNS,CONJUNCTIVITIS.CENTRAL NERVOUS SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:TARGET ORGANS:NO DATA AVAILABLE.

First Aid:INHAL:REMOVE FRM EXPO TO FRESH AIR IMMED.PERFORM ART RESP IF
NECESSARY.KEEP WARM/@REST.TREAT SYMPT/SUPPROT.SKIN:REMOVE CONTAM
CLOTH/SHOES IMMED.WASH W/SOAP/MILD DETERGENT/LG ATMS OF WATER TIL
NO EVIDE NCE OF CHEM REMAINS(@LEAST 15-20MINS).EYE:WASH IMMED W/LG
AMTS OF WATER OR NORMAL SALINE,LIFT LIDS OCCASIONALLY,TIL NO
EVIDENCE OF CHEM REMAINS(@LEAST 15-20MINS).INGEST:VOMIT OCCURS HELP
PREVENT(SUPP)

Flash Point Method:CC
Flash Point:340F,171C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:2.4
Upper Limits:NP
Extinguishing Media:DRY CHEM,CO2,WATERSPRAU,REG FOAM.LG FIRE:USE
WATERSPRAY,FOG,REG FOAM.
Fire Fighting Procedures:MOVE CNTNR FRM FIRE AREA W/O RISK.DONT SCTTER
SPILL MATL W/HIGH-PRESSURE WATER STREAMS.DIKE FIRE-CONTROL WATER
FOR LATER DISPO.USE AGENTS SUITABLE FOR TYP(SUPP)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME.

Spill Release Procedures:SWEEP UP & PLACE IN SUITABLE CLEAN,DRY
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL.DONT FLUSH SPILLED
MATL INTO SEWER.KEEP UNNECESSARY PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN
STORING OF THIS SUBSTANCE.
Other Precautions:ANTIDOTE:NO SPECIFIC ANTIDOTE.TREAT
SYMPTOMATICALLY/SUPPROTIVELY.

Respiratory Protection:SPEC RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORKPLACE/BASED ON SPEC OPERATION/NOT EXCEED WORK
LIMITS OR RESP/JOINT APPROV NIOOSH/MSHA:TYP C SUPPAIR W/FULL FCPC
IN PRESS-DEMAND/+PRESS MO DE/HELMET/HOOD CONT FLOW-MODE;ETC.
Ventilation:PROVIDE LOC EXHAU/PROCESS ENCLOSURE VENTI.VENTI EQPMT
SHOULD BE EXPLO-PROOF IF EXPLO CONC OF DUST/VAP/FUME PRESENT.
Protective Gloves:MUST WEAR APPROP PROT GLOVE
Eye Protection:MUST WEAR SPLASH-PROOF/DUST-RESIST(WORK)
Other Protective Equipment:MUST WEAR APPROP PROT(IMPERV)CLOTH/EQPMT TO
PREVENT REP/PROL SKIN CONTACT W/SUBST.EYEWASH FOUNTAIN W/IN IMMED
WORKAREA.
Work Hygienic Practices:EYE:SAF GOGG.
Supplemental Safety and Health
FIREFIGHT:OF SURROUNDING FIRE.AVOID BREATH HAZ VAP,KEEP UPWIND.
HEALTH:INGEST:MAY CAUSE CNS DEPRESS.CHRONIC:CARC STUDY FOUND NO
CONVINC EVIDENCE IN ANIMALS;HOWEVER ALVEOLAR/BRONCHIOLAR CARC/BRAIN
TUMO RS SUGG POSSIBLE CARC EFFECT. 1STAID:15-20MINS).GET MED ATTN
IMMED.INGEST:ASPIRATION.IN ALL CASES GET MED ATTN IMMED.

HCC:T4
Boiling Pt:B.P. Text:662F,350C
Melt/Freeze Pt:M.P/F.P Text:208F,98C
Decomp Temp:Decomp Text:NP
Vapor Pres:0.04
Vapor Density:4.1
Spec Gravity:1.36
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:1-10%
Appearance and Odor:WHITE TO PALE YELLOW OR LIGHT TAN,CRYSTALLINE
POWDER/FLAKES,NO/SLIGHT CHAR ODOR
Percent Volatiles by Volume:0
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
OXIDIZERS(STRONG):FIRE & EXPLOSION HAZARD.
Stability Condition to Avoid:MAY DETONATE @220C OR DURING VACUUM
DISTILLATION.MAY BURN BUT DOESNT IGN READILY.AVOID STRO OXID/EXCESS
HEAT/SPARK/OPFLM
Hazardous Decomposition Products:THERM DECOMPO PROD MAY INCLUDE HIGHLY
TOXIC FUMES OF HYDRYOGEN CYANIDE & TOXIC OXIDES OF CARBON &
NITROGEN.

Waste Disposal Methods:OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS
WHEN DISPOSING THIS SUBSTANCE.DISPOSAL MUST BE IAW STDS APPLICABLE
TO GENERATORS OF HAZ WASTE 40CFR262,EPA HAZ WASTE #:D003.100LBS
CERCLA SEC 103 RQ.

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particular situation.